尿素,英文名稱為Urea,化學名稱為脲或碳酰胺。結構式為CO(NH2或NH2CONH2,分子式為CH4ON2,相對分子質量為60.056。純尿素含氮46.65%(質量分數),是含氮量最高的氮肥。
尿素生產(chan)(chan)工(gong)(gong)藝(yi)流(liu)程(cheng)(cheng)基本(ben)由(you)6個工(gong)(gong)藝(yi)單元(yuan),即(ji)原(yuan)料供應、尿素的(de)高壓合成、含尿素溶液(ye)(ye)(ye)的(de)分(fen)離(li)過(guo)程(cheng)(cheng)、未(wei)反應氨和二氧(yang)化碳(tan)的(de)回收、尿素溶液(ye)(ye)(ye)的(de)濃縮(suo)、造粒與產(chan)(chan)品輸送(song)和工(gong)(gong)藝(yi)冷凝液(ye)(ye)(ye)處理(li),其(qi)基本(ben)過(guo)程(cheng)(cheng)如(ru)圖5-116所示(shi)。原(yuan)料CO2和NH3被加壓送(song)到高壓合成圈,反應生成尿素,二氧(yang)化碳(tan)轉(zhuan)(zhuan)化率在50%~75%,此(ci)過(guo)程(cheng)(cheng)被稱(cheng)為(wei)合成工(gong)(gong)序(xu);分(fen)離(li)過(guo)程(cheng)(cheng)與未(wei)反應物回收單元(yuan)承擔著(zhu)把(ba)未(wei)轉(zhuan)(zhuan)化為(wei)尿素的(de)氨和二氧(yang)化碳(tan)從溶液(ye)(ye)(ye)中(zhong)分(fen)離(li)出來,并(bing)回收返回合成工(gong)(gong)序(xu),因此(ci)這兩個單元(yuan)被統稱(cheng)為(wei)循(xun)環工(gong)(gong)序(xu);最后在真空蒸發和造粒設備中(zhong)把(ba)70%~75%的(de)尿素溶液(ye)(ye)(ye)經(jing)濃縮(suo)加工(gong)(gong)為(wei)固體產(chan)(chan)品,稱(cheng)為(wei)最終加工(gong)(gong)工(gong)(gong)序(xu)。
盡(jin)管(guan)尿素(su)生產(chan)的(de)(de)(de)(de)基本過程(cheng)(cheng)(cheng)(cheng)相似,但(dan)在(zai)(zai)具(ju)體(ti)的(de)(de)(de)(de)流程(cheng)(cheng)(cheng)(cheng)、工(gong)(gong)(gong)(gong)藝(yi)(yi)條(tiao)件、設備(bei)結構等(deng)(deng)方(fang)面,不同(tong)工(gong)(gong)(gong)(gong)藝(yi)(yi)存在(zai)(zai)一定(ding)的(de)(de)(de)(de)差異。迄今世界(jie)各地的(de)(de)(de)(de)尿素(su)工(gong)(gong)(gong)(gong)廠(chang),絕大多數都是(shi)(shi)由幾(ji)家工(gong)(gong)(gong)(gong)程(cheng)(cheng)(cheng)(cheng)設計(ji)公(gong)(gong)(gong)司(si)所開發設計(ji)的(de)(de)(de)(de),已形成幾(ji)種典型(xing)的(de)(de)(de)(de)工(gong)(gong)(gong)(gong)藝(yi)(yi)流程(cheng)(cheng)(cheng)(cheng),典型(xing)的(de)(de)(de)(de)有荷蘭斯太米卡(ka)邦(Stamicarbon)公(gong)(gong)(gong)司(si)的(de)(de)(de)(de)水溶(rong)液全(quan)循環CO2氣提(ti)法(fa)、意大利斯納姆(Snamprogetti)公(gong)(gong)(gong)司(si)的(de)(de)(de)(de)氨汽提(ti)法(fa)和(he)蒙特愛(ai)迪生集團公(gong)(gong)(gong)司(si)的(de)(de)(de)(de)等(deng)(deng)壓(ya)雙循環工(gong)(gong)(gong)(gong)藝(yi)(yi)(IDR)、日(ri)本三(san)井東(dong)亞-東(dong)洋工(gong)(gong)(gong)(gong)程(cheng)(cheng)(cheng)(cheng)公(gong)(gong)(gong)司(si)的(de)(de)(de)(de)全(quan)循環改(gai)良C法(fa)和(he)改(gai)良D法(fa)及ACES法(fa)、美國尿素(su)技(ji)術公(gong)(gong)(gong)司(si)UTI的(de)(de)(de)(de)熱循環法(fa)尿素(su)工(gong)(gong)(gong)(gong)藝(yi)(yi)(HR)等(deng)(deng)。但(dan)不論是(shi)(shi)哪種工(gong)(gong)(gong)(gong)藝(yi)(yi)流程(cheng)(cheng)(cheng)(cheng),生產(chan)過程(cheng)(cheng)(cheng)(cheng)中主(zhu)要(yao)原料NH3和(he)CO2的(de)(de)(de)(de)消耗(hao)基本上(shang)是(shi)(shi)相同(tong)的(de)(de)(de)(de),其流程(cheng)(cheng)(cheng)(cheng)的(de)(de)(de)(de)先(xian)進與否主(zhu)要(yao)表現在(zai)(zai)公(gong)(gong)(gong)用(yong)工(gong)(gong)(gong)(gong)程(cheng)(cheng)(cheng)(cheng),即水、電、汽的(de)(de)(de)(de)消耗(hao)上(shang)。尿素(su)生產(chan)流程(cheng)(cheng)(cheng)(cheng)的(de)(de)(de)(de)改(gai)進過程(cheng)(cheng)(cheng)(cheng),實質就是(shi)(shi)公(gong)(gong)(gong)用(yong)工(gong)(gong)(gong)(gong)程(cheng)(cheng)(cheng)(cheng)消耗(hao)降低的(de)(de)(de)(de)過程(cheng)(cheng)(cheng)(cheng)。
目前國內建有尿素裝置200多套,規模分為大型(48萬噸/年以上)、中型(11萬噸/年以上)、小型(4萬噸/年以上)。中、小型尿素裝置均采用國內的水溶液全循環技術,大型裝置多采用國外引進工藝技術。在國內的大型尿素裝置工藝技術中,多數采用CO2汽提工藝和氨汽提工藝。
目前設計的(de)(de)采用CO2汽(qi)提(ti)工藝和氨(an)汽(qi)提(ti)工藝的(de)(de)尿(niao)素(su)裝置,其尿(niao)素(su)氨(an)耗(hao)(hao)基本(ben)接近于理論水(shui)平,公(gong)用工程消耗(hao)(hao)更低,相對于傳統的(de)(de)設計,其投資(zi)更低。下面僅介紹 Snamprogetti 氨(an)汽(qi)提(ti)法尿(niao)素(su)工藝。
意大利斯納姆公司創立于1956年(nian),在(zai)20世紀60年(nian)代(dai)(dai)初開始尿素(su)生產(chan)的(de)(de)(de)研究(jiu)。1966年(nian)第一個(ge)(ge)建成(cheng)以氨作為汽(qi)(qi)(qi)提(ti)氣的(de)(de)(de)日產(chan)70t的(de)(de)(de)尿素(su)裝置。早(zao)期第一代(dai)(dai)氨汽(qi)(qi)(qi)提(ti)法(fa)尿素(su)裝置,設(she)備采用框架式立體布置,氨直(zhi)接加入(ru)汽(qi)(qi)(qi)提(ti)塔底部。在(zai)20世紀70年(nian)代(dai)(dai)中(zhong)期,改進了設(she)計,設(she)備改為平(ping)面布置,而且也不向(xiang)汽(qi)(qi)(qi)提(ti)塔直(zhi)接加入(ru)氨氣,這就(jiu)是所(suo)謂的(de)(de)(de)自汽(qi)(qi)(qi)提(ti)工藝(yi)(yi)或稱(cheng)為第二代(dai)(dai)氨汽(qi)(qi)(qi)提(ti)工藝(yi)(yi),是目前(qian)采用的(de)(de)(de)方法(fa)。斯納姆氨汽(qi)(qi)(qi)提(ti)法(fa)尿素(su)工藝(yi)(yi)由以下幾個(ge)(ge)主要工序組成(cheng)。
①. CO2氣體的壓縮。
②. 液氨(an)的加壓。
③. 高壓(ya)合成與氨(an)汽提回收。
④. 中壓分解與(yu)循環回收(shou)。
⑤. 低壓分解與循(xun)環回(hui)收。
⑥. 中(zhong)、低(di)壓分解與循(xun)環回(hui)收。
⑦. 真(zhen)空蒸(zheng)發與造粒。
⑧. 解(jie)吸與(yu)水解(jie)系統。
氨汽提(ti)法(fa)尿素生產工藝(yi)流程、如圖5-117所示。