電(dian)(dian)火(huo)(huo)花表(biao)(biao)面強(qiang)化(hua)是利用(yong)工(gong)具電(dian)(dian)極與(yu)工(gong)件(jian)間在氣體(ti)中產生的(de)(de)火(huo)(huo)花放電(dian)(dian)作用(yong),把作為電(dian)(dian)極的(de)(de)導電(dian)(dian)材料(liao)熔滲進工(gong)件(jian)表(biao)(biao)層,形成合金(jin)化(hua)的(de)(de)表(biao)(biao)面強(qiang)化(hua)層,改(gai)善工(gong)件(jian)表(biao)(biao)面的(de)(de)物理及化(hua)學性(xing)能。
電火花表面強化層的性能主要決定于模具本身和電極材料,通常所用的電極材料有TiC、WC、ZrC、NbC、Cr3C2、硬質合金等。電火花強化表面因電極材料的沉積發生有規律的、較小的長大,除此之外,模具沒有其他變形。其心部的組織與性能也不發生變化,因此十分適用于工件表面強化處理。
金屬電(dian)(dian)(dian)火(huo)花(hua)表面(mian)強(qiang)化的(de)原理(li)是(shi)在工(gong)具電(dian)(dian)(dian)極(ji)與工(gong)件之間(jian)(jian)接上直(zhi)流電(dian)(dian)(dian)源或(huo)交流電(dian)(dian)(dian)源,由于振(zhen)動器的(de)作(zuo)用(yong)使電(dian)(dian)(dian)極(ji)與工(gong)件間(jian)(jian)的(de)放電(dian)(dian)(dian)間(jian)(jian)隙(xi)頻繁變化,工(gong)具電(dian)(dian)(dian)極(ji)與工(gong)件間(jian)(jian)不斷產生火(huo)花(hua)放電(dian)(dian)(dian),從而實現(xian)對金屬表面(mian)的(de)強(qiang)化。
電(dian)(dian)(dian)(dian)(dian)(dian)(dian)火花(hua)強(qiang)(qiang)化(hua)過(guo)程如圖(tu)(tu)3-20所(suo)示。當(dang)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)極(ji)(ji)(ji)與(yu)工(gong)件(jian)(jian)(jian)(jian)之(zhi)間的(de)(de)(de)距離較(jiao)大時(shi),電(dian)(dian)(dian)(dian)(dian)(dian)(dian)源經電(dian)(dian)(dian)(dian)(dian)(dian)(dian)阻R對電(dian)(dian)(dian)(dian)(dian)(dian)(dian)容充電(dian)(dian)(dian)(dian)(dian)(dian)(dian),電(dian)(dian)(dian)(dian)(dian)(dian)(dian)極(ji)(ji)(ji)在振(zhen)動(dong)器的(de)(de)(de)帶動(dong)下向模(mo)具靠近(jin)(見圖(tu)(tu)3-20a)。當(dang)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)極(ji)(ji)(ji)與(yu)模(mo)具之(zhi)間的(de)(de)(de)間隙接(jie)近(jin)到某(mou)個距離時(shi),間隙中的(de)(de)(de)空氣在強(qiang)(qiang)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)場的(de)(de)(de)作用下電(dian)(dian)(dian)(dian)(dian)(dian)(dian)離,產(chan)生火花(hua)放(fang)(fang)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(見圖(tu)(tu)3-20b),使電(dian)(dian)(dian)(dian)(dian)(dian)(dian)極(ji)(ji)(ji)和工(gong)件(jian)(jian)(jian)(jian)在發生放(fang)(fang)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)部分的(de)(de)(de)金屬局部熔化(hua),甚至汽化(hua)。電(dian)(dian)(dian)(dian)(dian)(dian)(dian)極(ji)(ji)(ji)繼(ji)(ji)續(xu)接(jie)近(jin)工(gong)件(jian)(jian)(jian)(jian)并與(yu)工(gong)件(jian)(jian)(jian)(jian)接(jie)觸時(shi),火花(hua)放(fang)(fang)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)停(ting)止,在接(jie)觸點流(liu)過(guo)短(duan)路(lu)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)流(liu),使該處繼(ji)(ji)續(xu)加(jia)熱(re),由(you)于電(dian)(dian)(dian)(dian)(dian)(dian)(dian)極(ji)(ji)(ji)以適(shi)當(dang)壓力壓向工(gong)件(jian)(jian)(jian)(jian),使熔化(hua)的(de)(de)(de)材料互相粘接(jie)、擴散而形成合(he)金或新的(de)(de)(de)化(hua)合(he)物(wu)(見圖(tu)(tu)3-20c)。電(dian)(dian)(dian)(dian)(dian)(dian)(dian)極(ji)(ji)(ji)在振(zhen)動(dong)器的(de)(de)(de)作用下,離開(kai)了工(gong)件(jian)(jian)(jian)(jian),放(fang)(fang)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)部分急劇冷卻(見圖(tu)(tu)3-20d)。經多(duo)次(ci)放(fang)(fang)電(dian)(dian)(dian)(dian)(dian)(dian)(dian),并相應地移動(dong)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)極(ji)(ji)(ji)的(de)(de)(de)位(wei)置,則在零件(jian)(jian)(jian)(jian)表(biao)面形成強(qiang)(qiang)化(hua)層(ceng)。
電火(huo)(huo)花表面強化過程中發生了物(wu)理(li)化學(xue)變化,主(zhu)要包括超(chao)高(gao)速淬火(huo)(huo)、滲碳、滲氮、電極材(cai)料的轉移(yi)等。
a. 超高速淬火
電(dian)火花放(fang)電(dian)在(zai)模具表面的(de)極小面積上產生高溫,使(shi)該處的(de)金屬(shu)熔化和(he)部分(fen)汽化,當火花放(fang)電(dian)在(zai)極短(duan)的(de)時間內停止后,被加熱了的(de)金屬(shu)會以很快的(de)速度冷卻下來。這相(xiang)當于對模具表面層(ceng)進行了超速淬火。
b. 滲(shen)氮
在(zai)電火花放電通道區(qu)域內,溫度很高(gao)(gao),空氣中的氮(dan)分(fen)子(zi)呈原子(zi)狀態,它和(he)受高(gao)(gao)溫而熔(rong)化的金(jin)屬有關的元素合成(cheng)高(gao)(gao)硬度的金(jin)屬氮(dan)化物,如氮(dan)化鐵、氮(dan)化鉻等。
c. 滲碳
來自石墨電(dian)極或周圍介質的(de)碳(tan)(tan)元素,熔解在受熱而熔化的(de)鐵中,形成金屬的(de)碳(tan)(tan)化物,如碳(tan)(tan)化鐵、碳(tan)(tan)化鉻等。
d. 電極材料的轉(zhuan)移
在操作壓力和火花放電的條(tiao)件下,電極材料轉(zhuan)移到模(mo)具金屬熔融表(biao)面,有關金屬合金元素(W、Ti、Cr等)迅速(su)擴散在金屬的表(biao)面層。
電火花表面強化層(ceng)具有如下特征:
a. 當(dang)采(cai)用硬質合金(jin)作電(dian)極(ji)材(cai)料時,硬度可(ke)達1100~1400HV(約(yue)70HRC以上)或更高,耐熱(re)性(xing)、耐蝕性(xing)和疲(pi)勞(lao)強(qiang)度都大大提高。
b. 當使用鉻(ge)錳、鎢鉻(ge)鈷合(he)金、硬質合(he)金作工(gong)具電(dian)極強化(hua)45鋼時,其耐磨性比原(yuan)表層提高2~2.5倍。
c. 用石墨(mo)作電極材料強化45鋼(gang),用食鹽水(shui)作腐蝕性試驗,其(qi)耐蝕性提高90%;用WC、CrMn作電極強化不(bu)銹鋼(gang)時(shi),其(qi)耐蝕性提高3~5倍。
d. 硬化層(ceng)厚(hou)度為0.01~0.08mm。
鋼制模(mo)具工(gong)作表(biao)面(mian)(mian)的電(dian)火花(hua)強化(hua)通常(chang)采用硬質合金電(dian)極(ji)。為了使(shi)被強化(hua)的表(biao)面(mian)(mian)光潔,事先必須將(jiang)模(mo)具和電(dian)極(ji)表(biao)面(mian)(mian)清洗(xi)干凈,然后手持(chi)(chi)振動器(qi),將(jiang)電(dian)極(ji)沿模(mo)具工(gong)作表(biao)面(mian)(mian)移動,并保(bao)持(chi)(chi)適當(dang)壓力,使(shi)火花(hua)放(fang)電(dian)均勻連續(xu)。
電火花熔滲(shen)合金化層(ceng)的(de)形成是一(yi)個漸近過程(cheng),在(zai)每一(yi)電規范下,合金化層(ceng)厚度出(chu)現最(zui)大(da)值,在(zai)通常使用(yong)的(de)電容范圍內,最(zui)佳單位(wei)面積涂覆時間為6~12min/c㎡。過分(fen)延(yan)長涂覆時間將出(chu)現層(ceng)厚減薄(bo)的(de)趨勢,并使性能惡化。可用(yong)直(zhi)線方程(cheng)式表示:
如電(dian)極YG8、電(dian)壓(ya)60V,頻率250Hz,電(dian)容60μF,最佳(jia)涂覆時間(jian)為6.75min/c㎡,合金化(hua)層厚(hou)度(du)為13μm;電(dian)容322μF,涂覆時間(jian)為11.99min/c㎡,合金化(hua)層厚(hou)度(du)為27μm。
為了降低合(he)(he)金(jin)(jin)化層的(de)(de)熱疲勞(lao)應(ying)力和電(dian)火(huo)(huo)花合(he)(he)金(jin)(jin)化處(chu)理(li)的(de)(de)應(ying)力,可(ke)穿插1~2次500℃×4h去應(ying)力退(tui)火(huo)(huo),這(zhe)樣可(ke)獲(huo)得(de)性能優良、層深較厚的(de)(de)表面(mian)合(he)(he)金(jin)(jin)化層。改換電(dian)極(ji)材(cai)料,可(ke)使(shi)合(he)(he)金(jin)(jin)化層繼續增(zeng)厚,電(dian)極(ji)斷(duan)面(mian)尺寸(cun)不影響合(he)(he)金(jin)(jin)化層的(de)(de)厚度。鋼(gang)中(zhong)w(C)小于0.8%時(shi)(shi),隨(sui)鋼(gang)中(zhong)碳(tan)含(han)量(liang)(liang)的(de)(de)增(zeng)加合(he)(he)金(jin)(jin)層增(zeng)厚;w(C)大于0.8%時(shi)(shi),隨(sui)鋼(gang)中(zhong)碳(tan)含(han)量(liang)(liang)的(de)(de)增(zeng)加合(he)(he)金(jin)(jin)層變(bian)薄。
用YG8、Nb、Ti、Ta合金化(hua),工(gong)件表面將獲得極高的顯(xian)微硬度值。
電火花合(he)(he)金(jin)(jin)層比(bi)未經電火花合(he)(he)金(jin)(jin)化處理(li)的模具的熱疲勞性能提高3倍,抗氧(yang)化性能提高兩倍,在各種試驗介質中(zhong)的耐(nai)蝕性提高3~15倍;表(biao)3-44所示(shi)為3Cr2W8V鋼的處理(li)效果(guo)。
電(dian)火花表(biao)面強化(hua)(hua)應用效果顯著(zhu)。例如用YG8作電(dian)極,對3Cr2W8V鋼模(mo)(mo)具進行電(dian)火花強化(hua)(hua)處理(li)以后(hou),模(mo)(mo)具在(zai)各(ge)類酸堿中的(de)耐蝕性提高(gao)(gao)4~15倍;而(er)Cr12鋼模(mo)(mo)具刃口部位經電(dian)火花表(biao)面強化(hua)(hua)后(hou),模(mo)(mo)具的(de)平均(jun)使用壽命由5萬次(ci)提高(gao)(gao)到20萬次(ci)。