按照氫脆敏感性與應變速率的關系,可以將氫致開裂分為兩大類。
1. 第(di)一類(lei)氫(qing)脆
氫脆的敏感性隨應變速率的增加而增加,即材料加載前內部已存在某種裂紋源,加載后在應力作用下加快了裂紋的形成與擴展。第一類氫脆包括三種形式:①. 氫腐蝕,由于氫在高溫高壓下與金屬中第二相(夾雜物和合金添加物)發生化學反應,生成高壓氣體(如CH4、SiH4)引起材料脫碳、內裂紋和鼓泡的現象;②. 氫鼓泡,過飽和的氫原子在缺陷位置(如夾雜)析出,形成氫分子,在局部造成很高的氫壓,引起表面鼓泡或內部裂紋的現象;③. 氫化物型氫脆,氫與IVB和VB族金屬有較大的親和力,氫含量較高時容易產生脆性的氫化物相,并在隨后受力時成為裂紋源,引起脆斷。
上述(shu)三(san)種(zhong)情況(kuang)將造成(cheng)金屬(shu)永久損(sun)傷,使材(cai)料塑性或(huo)(huo)強(qiang)度降低,即使從(cong)金屬(shu)中除(chu)氫損(sun)傷也不能消除(chu),塑性或(huo)(huo)強(qiang)度也不能恢復,故(gu)稱為不可逆氫脆。
2. 第二類氫脆
氫(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)的(de)(de)(de)敏(min)感性(xing)(xing)(xing)(xing)隨(sui)應(ying)(ying)(ying)(ying)(ying)變速(su)率增加而降低(di),即(ji)材料在(zai)(zai)(zai)(zai)加載(zai)前并不存(cun)在(zai)(zai)(zai)(zai)裂紋源(yuan),加載(zai)后在(zai)(zai)(zai)(zai)應(ying)(ying)(ying)(ying)(ying)力(li)和(he)氫(qing)(qing)(qing)的(de)(de)(de)交互作(zuo)(zuo)用下(xia)(xia)逐漸形(xing)成裂紋源(yuan),最(zui)終導(dao)致(zhi)脆(cui)(cui)(cui)(cui)性(xing)(xing)(xing)(xing)斷裂。第二類氫(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)包括兩種形(xing)式(shi):一是(shi)(shi)(shi)應(ying)(ying)(ying)(ying)(ying)力(li)誘(you)(you)發氫(qing)(qing)(qing)化(hua)物(wu)型(xing)氫(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。在(zai)(zai)(zai)(zai)能(neng)夠形(xing)成脆(cui)(cui)(cui)(cui)性(xing)(xing)(xing)(xing)氫(qing)(qing)(qing)化(hua)物(wu)的(de)(de)(de)金(jin)屬中(zhong),當(dang)氫(qing)(qing)(qing)含量(liang)較(jiao)低(di)或(huo)氫(qing)(qing)(qing)在(zai)(zai)(zai)(zai)固溶體中(zhong)的(de)(de)(de)過飽和(he)度(du)較(jiao)低(di)時(shi)(shi),尚不能(neng)自發形(xing)成氫(qing)(qing)(qing)化(hua)物(wu);而在(zai)(zai)(zai)(zai)應(ying)(ying)(ying)(ying)(ying)力(li)作(zuo)(zuo)用下(xia)(xia),氫(qing)(qing)(qing)會向應(ying)(ying)(ying)(ying)(ying)力(li)集中(zhong)處(chu)富集,當(dang)氫(qing)(qing)(qing)濃度(du)超過臨界值時(shi)(shi)就(jiu)會沉淀出氫(qing)(qing)(qing)化(hua)物(wu)。這(zhe)種應(ying)(ying)(ying)(ying)(ying)力(li)誘(you)(you)發的(de)(de)(de)氫(qing)(qing)(qing)化(hua)物(wu)相(xiang)變只在(zai)(zai)(zai)(zai)較(jiao)低(di)的(de)(de)(de)應(ying)(ying)(ying)(ying)(ying)變速(su)率下(xia)(xia)出現(xian)(xian),并由(you)此(ci)導(dao)致(zhi)脆(cui)(cui)(cui)(cui)性(xing)(xing)(xing)(xing)斷裂,一旦(dan)出現(xian)(xian)氫(qing)(qing)(qing)化(hua)物(wu),即(ji)使(shi)卸載(zai)除氫(qing)(qing)(qing),靜(jing)止一段時(shi)(shi)間后再高(gao)速(su)變形(xing),塑(su)性(xing)(xing)(xing)(xing)也不能(neng)恢復(fu),故也是(shi)(shi)(shi)不可逆(ni)氫(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。二是(shi)(shi)(shi)可逆(ni)氫(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。是(shi)(shi)(shi)指(zhi)含氫(qing)(qing)(qing)金(jin)屬在(zai)(zai)(zai)(zai)高(gao)速(su)變形(xing)時(shi)(shi)并不顯示脆(cui)(cui)(cui)(cui)性(xing)(xing)(xing)(xing),而在(zai)(zai)(zai)(zai)緩慢(man)變形(xing)時(shi)(shi)由(you)于氫(qing)(qing)(qing)逐漸向應(ying)(ying)(ying)(ying)(ying)力(li)集中(zhong)處(chu)富集,在(zai)(zai)(zai)(zai)應(ying)(ying)(ying)(ying)(ying)力(li)與氫(qing)(qing)(qing)交互作(zuo)(zuo)用下(xia)(xia)裂紋形(xing)核、擴展,最(zui)終導(dao)致(zhi)脆(cui)(cui)(cui)(cui)性(xing)(xing)(xing)(xing)的(de)(de)(de)斷裂,在(zai)(zai)(zai)(zai)未形(xing)成裂紋前去除載(zai)荷(he),靜(jing)置一段時(shi)(shi)間后高(gao)速(su)變形(xing),材料的(de)(de)(de)塑(su)性(xing)(xing)(xing)(xing)可以得到恢復(fu),即(ji)應(ying)(ying)(ying)(ying)(ying)力(li)去除后脆(cui)(cui)(cui)(cui)性(xing)(xing)(xing)(xing)消失,因此(ci)稱(cheng)為可逆(ni)氫(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。由(you)內氫(qing)(qing)(qing)引(yin)起(qi)的(de)(de)(de)稱(cheng)可逆(ni)內氫(qing)(qing)(qing)脆(cui)(cui)(cui)(cui),由(you)外氫(qing)(qing)(qing)引(yin)起(qi)的(de)(de)(de)稱(cheng)環境氫(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。通常所說的(de)(de)(de)氫(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)主要指(zhi)可逆(ni)氫(qing)(qing)(qing)脆(cui)(cui)(cui)(cui),是(shi)(shi)(shi)氫(qing)(qing)(qing)致(zhi)開裂中(zhong)最(zui)主要、最(zui)危險的(de)(de)(de)破壞形(xing)式(shi)。

