按照氫脆敏感性與應變速率的關系,可以將氫致開裂分為兩大類。


1. 第一類氫(qing)脆


 氫脆的敏感性隨應變速率的增加而增加,即材料加載前內部已存在某種裂紋源,加載后在應力作用下加快了裂紋的形成與擴展。第一類氫脆包括三種形式:①. 氫腐蝕,由于氫在高溫高壓下與金屬中第二相(夾雜物和合金添加物)發生化學反應,生成高壓氣體(如CH4、SiH4)引起材料脫碳、內裂紋和鼓泡的現象;②. 氫鼓泡,過飽和的氫原子在缺陷位置(如夾雜)析出,形成氫分子,在局部造成很高的氫壓,引起表面鼓泡或內部裂紋的現象;③. 氫化物型氫脆,氫與IVB和VB族金屬有較大的親和力,氫含量較高時容易產生脆性的氫化物相,并在隨后受力時成為裂紋源,引起脆斷。


 上述三種情況將造成金(jin)屬(shu)永久損(sun)傷,使材料塑(su)(su)性或(huo)強(qiang)度降低,即使從金(jin)屬(shu)中除(chu)氫(qing)損(sun)傷也不能消除(chu),塑(su)(su)性或(huo)強(qiang)度也不能恢復,故稱為不可逆氫(qing)脆。


2. 第二類(lei)氫脆


 氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)的(de)(de)(de)敏感性(xing)隨應變速率(lv)增加而(er)降低(di)(di),即材(cai)(cai)料在(zai)(zai)(zai)(zai)加載(zai)前并不(bu)(bu)存在(zai)(zai)(zai)(zai)裂(lie)(lie)紋(wen)(wen)源,加載(zai)后(hou)在(zai)(zai)(zai)(zai)應力(li)(li)和(he)氫(qing)(qing)(qing)(qing)(qing)(qing)的(de)(de)(de)交互作(zuo)(zuo)用下(xia)(xia)逐(zhu)漸形(xing)(xing)(xing)(xing)成(cheng)(cheng)裂(lie)(lie)紋(wen)(wen)源,最終(zhong)(zhong)導(dao)致(zhi)脆(cui)(cui)(cui)(cui)性(xing)斷裂(lie)(lie)。第二類(lei)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)包括兩種形(xing)(xing)(xing)(xing)式(shi):一(yi)是(shi)應力(li)(li)誘發(fa)氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)物型氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。在(zai)(zai)(zai)(zai)能(neng)夠形(xing)(xing)(xing)(xing)成(cheng)(cheng)脆(cui)(cui)(cui)(cui)性(xing)氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)物的(de)(de)(de)金(jin)屬中,當氫(qing)(qing)(qing)(qing)(qing)(qing)含(han)量(liang)較低(di)(di)或(huo)氫(qing)(qing)(qing)(qing)(qing)(qing)在(zai)(zai)(zai)(zai)固溶體中的(de)(de)(de)過飽和(he)度較低(di)(di)時,尚(shang)不(bu)(bu)能(neng)自發(fa)形(xing)(xing)(xing)(xing)成(cheng)(cheng)氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)物;而(er)在(zai)(zai)(zai)(zai)應力(li)(li)作(zuo)(zuo)用下(xia)(xia),氫(qing)(qing)(qing)(qing)(qing)(qing)會向應力(li)(li)集(ji)中處富(fu)集(ji),當氫(qing)(qing)(qing)(qing)(qing)(qing)濃(nong)度超過臨界值時就會沉(chen)淀出氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)物。這(zhe)種應力(li)(li)誘發(fa)的(de)(de)(de)氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)物相變只在(zai)(zai)(zai)(zai)較低(di)(di)的(de)(de)(de)應變速率(lv)下(xia)(xia)出現(xian),并由(you)(you)(you)(you)此導(dao)致(zhi)脆(cui)(cui)(cui)(cui)性(xing)斷裂(lie)(lie),一(yi)旦出現(xian)氫(qing)(qing)(qing)(qing)(qing)(qing)化(hua)(hua)物,即使卸載(zai)除(chu)氫(qing)(qing)(qing)(qing)(qing)(qing),靜止一(yi)段時間后(hou)再高速變形(xing)(xing)(xing)(xing),塑(su)性(xing)也不(bu)(bu)能(neng)恢復,故(gu)也是(shi)不(bu)(bu)可(ke)逆(ni)(ni)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。二是(shi)可(ke)逆(ni)(ni)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。是(shi)指(zhi)含(han)氫(qing)(qing)(qing)(qing)(qing)(qing)金(jin)屬在(zai)(zai)(zai)(zai)高速變形(xing)(xing)(xing)(xing)時并不(bu)(bu)顯示脆(cui)(cui)(cui)(cui)性(xing),而(er)在(zai)(zai)(zai)(zai)緩慢變形(xing)(xing)(xing)(xing)時由(you)(you)(you)(you)于(yu)氫(qing)(qing)(qing)(qing)(qing)(qing)逐(zhu)漸向應力(li)(li)集(ji)中處富(fu)集(ji),在(zai)(zai)(zai)(zai)應力(li)(li)與氫(qing)(qing)(qing)(qing)(qing)(qing)交互作(zuo)(zuo)用下(xia)(xia)裂(lie)(lie)紋(wen)(wen)形(xing)(xing)(xing)(xing)核、擴展(zhan),最終(zhong)(zhong)導(dao)致(zhi)脆(cui)(cui)(cui)(cui)性(xing)的(de)(de)(de)斷裂(lie)(lie),在(zai)(zai)(zai)(zai)未形(xing)(xing)(xing)(xing)成(cheng)(cheng)裂(lie)(lie)紋(wen)(wen)前去(qu)除(chu)載(zai)荷(he),靜置一(yi)段時間后(hou)高速變形(xing)(xing)(xing)(xing),材(cai)(cai)料的(de)(de)(de)塑(su)性(xing)可(ke)以得到恢復,即應力(li)(li)去(qu)除(chu)后(hou)脆(cui)(cui)(cui)(cui)性(xing)消失,因此稱為(wei)可(ke)逆(ni)(ni)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。由(you)(you)(you)(you)內氫(qing)(qing)(qing)(qing)(qing)(qing)引(yin)起(qi)的(de)(de)(de)稱可(ke)逆(ni)(ni)內氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui),由(you)(you)(you)(you)外氫(qing)(qing)(qing)(qing)(qing)(qing)引(yin)起(qi)的(de)(de)(de)稱環境氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)。通常所說的(de)(de)(de)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui)主(zhu)要(yao)指(zhi)可(ke)逆(ni)(ni)氫(qing)(qing)(qing)(qing)(qing)(qing)脆(cui)(cui)(cui)(cui),是(shi)氫(qing)(qing)(qing)(qing)(qing)(qing)致(zhi)開裂(lie)(lie)中最主(zhu)要(yao)、最危險的(de)(de)(de)破壞形(xing)(xing)(xing)(xing)式(shi)。