不銹鋼的爐(lu)中(zhong)釬(han)焊一般是在(zai)某(mou)種保(bao)護性(xing)氣氛(fen)下(xia)或真空(kong)中(zhong)進行,保(bao)護氣氛(fen)有(you)氫(qing)氣、分解氨和(he)氬(ya)氣。
干燥的氫氣或分解氨常用做爐中釬(han)焊不銹鋼(gang)時的還原性保護氣氛,它們可還原不銹鋼表面的氧化膜,并保護不銹鋼表面在釬焊時不再氧化。一般要求氫氣或分解氨的露點低于-40℃,但也要考慮保護氣體的露點要與釬焊溫度及母材的成分相適應。釬焊溫度越低、不銹鋼表面氧化膜越穩定,要求氫氣露點越低,見圖3-4。使用分解氨作保護氣氛時,必須保證NH3完全分解,避免殘余的NH3使不銹鋼表面氮化。
使用氫氣或分解氨作保護氣氛的(de)好處(chu)是(shi):可(ke)(ke)實現(xian)釬(han)焊(han)爐的(de)連續工(gong)(gong)作,便于大批量生產;釬(han)焊(han)過程中不(bu)需(xu)使用釬(han)劑,且焊(han)后工(gong)(gong)件光亮,無需(xu)任(ren)何焊(han)后工(gong)(gong)件表(biao)面清理工(gong)(gong)作;可(ke)(ke)配合選(xuan)用的(de)釬(han)料(liao)品種多;在批量生產條件下焊(han)接成(cheng)本低。但是(shi)使用氫氣或分解氨作保護氣氛時要注意生產安全(quan),當空氣中混(hun)有4%~74%的(de)氫氣或12.5%~27%氨氣時,會(hui)因燃(ran)燒而產生爆炸。
作為惰(duo)性氣體,氬(ya)(ya)氣可(ke)用作爐中(zhong)釬(han)焊(han)(han)不(bu)銹(xiu)(xiu)鋼時的(de)保(bao)護氣氛。與氫氣和分解氨不(bu)同(tong),氬(ya)(ya)氣不(bu)具有還原(yuan)性,只是利用其(qi)惰(duo)性保(bao)護不(bu)銹(xiu)(xiu)鋼表(biao)面在(zai)釬(han)焊(han)(han)過程中(zhong)不(bu)氧化(hua)(hua),所以不(bu)銹(xiu)(xiu)鋼進爐釬(han)焊(han)(han)前必(bi)須徹底清除(chu)其(qi)表(biao)面的(de)氧化(hua)(hua)膜,并且一般要求氬(ya)(ya)氣的(de)露點低于-40℃。
使(shi)用(yong)氬氣(qi)作保護氣(qi)氛(fen)一(yi)般是因為以(yi)下某(mou)(mou)種或多種原因:①. 可采用(yong)含高蒸汽(qi)壓(ya)元素的釬,如(ru)錳(meng)基釬料或含錳(meng)較(jiao)多的釬料;②. 單件或小批(pi)量(liang)釬焊(han)時,設備成本低;③. 不銹鋼(gang)與異種材(cai)釬焊(han)時避免(mian)某(mou)(mou)些(xie)材(cai)料與爐內氣(qi)氛(fen)的反應,如(ru)在含氫氣(qi)氛(fen)中釬焊(han)連接不銹鋼(gang)與鈦合金時,鈦金吸氫并與氫反應;④. 生產過程安全。
使用氬氣作保護氣氛時,常見的做法是將真空爐抽至高真空后(10-2~10-3Pa)充入少量氬氣,關閉爐體氣閥后升溫。或者在特制的密封容器內通人流動的氬氣,將空氣趕凈后,容器放入馬弗爐內加熱。也可在趕凈空氣后,關閉氣路,容器放人馬弗爐內加熱,但在升溫過
程中要隨(sui)時(shi)(shi)注意(yi)(yi)容(rong)器(qi)內(nei)的(de)(de)(de)壓(ya)力,當容(rong)器(qi)內(nei)壓(ya)力超(chao)過大氣壓(ya)較多時(shi)(shi)應隨(sui)時(shi)(shi)放出(chu)一些氣體(ti)(ti),以(yi)(yi)保證容(rong)器(qi)完好和生產(chan)安全(quan)。使用(yong)特制的(de)(de)(de)容(rong)器(qi)還有另一個便利:當使用(yong)未經凈化(hua)的(de)(de)(de)普通瓶裝氬氣時(shi)(shi),可(ke)向釬(han)(han)(han)焊爐內(nei)通入少許BF3氣體(ti)(ti)釬(han)(han)(han)劑,或加(jia)入少許氟(fu)硼(peng)酸鉀,氟(fu)硼(peng)酸鉀在800~900℃分(fen)解產(chan)生BF3.BF3可(ke)以(yi)(yi)去除(chu)金屬表面的(de)(de)(de)氧(yang)化(hua)物,促進(jin)釬(han)(han)(han)料的(de)(de)(de)潤(run)濕。氣體(ti)(ti)釬(han)(han)(han)劑的(de)(de)(de)使用(yong)濃度一般(ban)控制在0.1%~0.001%(體(ti)(ti)積分(fen)數(shu)),避免焊后形成殘(can)渣(zha)。氟(fu)化(hua)物對人體(ti)(ti)有害,要注意(yi)(yi)工作場(chang)地的(de)(de)(de)通風。
在真空爐中釬焊不銹鋼是一種常用且理想的方法。釬焊不銹鋼時一般要求真空度達到10-2~10-3Pa,并且要求真空爐的氣體泄漏率小于10-2Pa/s.使用真空爐釬焊不銹鋼的好處是:可避免不銹鋼的氧化;可避免釬焊爐內氣氛對母材的不良影響;真空爐升、降溫速度慢,工件不變形或變形量很小;無論以何種方式添加釬料均不會在接頭內形成氣孔;無需消耗保護氣體;無需氣體凈化裝置;無安全隱患;帶有充氣及快冷風扇置的真空爐同樣具有較高的生產率,并可實現釬焊與焊后工件熱處理的結合。
在氫氣或分解氨氣氛爐中釬焊不銹鋼可使用紫銅、銅基、銀基、錳基、鎳基和金基釬料。在氬氣氛爐中釬焊不銹鋼可使用銅基、銀基、錳基、金基釬料。在真空爐中釬焊不銹鋼可采用紫銅、不含易蒸發元素(Zn、Cd)或僅含少量高蒸汽壓元素(Mn)的銅基和銀基釬料、鎳基釬料和金基釬料。使用鎳基釬料釬焊不銹鋼薄件時,要選擇對母材溶蝕傾向小的釬料。
爐中(zhong)(zhong)釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)時影(ying)響釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)接頭(tou)(tou)性(xing)(xing)(xing)能(neng),特別(bie)是(shi)(shi)力學性(xing)(xing)(xing)能(neng)的(de)(de)(de)主要工(gong)藝參數(shu)(shu)包(bao)釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)溫(wen)(wen)度(du)(du)(du)(du)(du)、保(bao)(bao)溫(wen)(wen)時間(jian)(jian)(jian)(jian)。釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)溫(wen)(wen)度(du)(du)(du)(du)(du)一(yi)(yi)(yi)般選擇在(zai)釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)液相(xiang)線溫(wen)(wen)度(du)(du)(du)(du)(du)以(yi)上50~100℃,保(bao)(bao)溫(wen)(wen)時間(jian)(jian)(jian)(jian)在(zai)5~10min.當工(gong)件(jian)較大時,可在(zai)升溫(wen)(wen)過程中(zhong)(zhong)釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)固相(xiang)線溫(wen)(wen)度(du)(du)(du)(du)(du)以(yi)下某(mou)溫(wen)(wen)度(du)(du)(du)(du)(du)保(bao)(bao)溫(wen)(wen)一(yi)(yi)(yi)段時間(jian)(jian)(jian)(jian),確(que)保(bao)(bao)工(gong)件(jian)溫(wen)(wen)度(du)(du)(du)(du)(du)均勻。使用鎳(nie)(nie)基釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)時,除了(le)釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)溫(wen)(wen)度(du)(du)(du)(du)(du)和(he)保(bao)(bao)溫(wen)(wen)時間(jian)(jian)(jian)(jian)外,釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)間(jian)(jian)(jian)(jian)隙(xi)(xi)(xi)也是(shi)(shi)接頭(tou)(tou)強(qiang)度(du)(du)(du)(du)(du)和(he)塑(su)性(xing)(xing)(xing)的(de)(de)(de)決定(ding)因(yin)素之一(yi)(yi)(yi)。圖3-5、圖3-6顯示了(le)三(san)種鎳(nie)(nie)基釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)不(bu)銹鋼時釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)接頭(tou)(tou)強(qiang)度(du)(du)(du)(du)(du)與釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)間(jian)(jian)(jian)(jian)隙(xi)(xi)(xi)的(de)(de)(de)關(guan)系。為降低釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)的(de)(de)(de)熔點,鎳(nie)(nie)基釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)中(zhong)(zhong)含有較多的(de)(de)(de)硼、硅(gui)(gui)(gui)、磷,它們在(zai)釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)組織(zhi)中(zhong)(zhong)以(yi)脆性(xing)(xing)(xing)的(de)(de)(de)硼化(hua)(hua)物(wu)(wu)、硅(gui)(gui)(gui)化(hua)(hua)物(wu)(wu)、磷化(hua)(hua)物(wu)(wu)形式(shi)存在(zai)。釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)時在(zai)一(yi)(yi)(yi)定(ding)的(de)(de)(de)釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)溫(wen)(wen)度(du)(du)(du)(du)(du)和(he)保(bao)(bao)溫(wen)(wen)時間(jian)(jian)(jian)(jian)下,當釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)間(jian)(jian)(jian)(jian)隙(xi)(xi)(xi)小(xiao)于某(mou)一(yi)(yi)(yi)數(shu)(shu)值,硼、硅(gui)(gui)(gui)、磷向母(mu)材擴散(san)充(chong)分,凝固后釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)組織(zhi)為鎳(nie)(nie)基固溶體,釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)強(qiang)度(du)(du)(du)(du)(du)高、塑(su)性(xing)(xing)(xing)好,此數(shu)(shu)值稱作該釬(han)(han)(han)(han)(han)(han)(han)(han)料(liao)在(zai)此釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)溫(wen)(wen)度(du)(du)(du)(du)(du)和(he)保(bao)(bao)溫(wen)(wen)時間(jian)(jian)(jian)(jian)下的(de)(de)(de)最(zui)大釬(han)(han)(han)(han)(han)(han)(han)(han)焊(han)間(jian)(jian)(jian)(jian)隙(xi)(xi)(xi)。當釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)間(jian)(jian)(jian)(jian)隙(xi)(xi)(xi)超過最(zui)大間(jian)(jian)(jian)(jian)隙(xi)(xi)(xi),釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)中(zhong)(zhong)硼、硅(gui)(gui)(gui)、磷向母(mu)材擴散(san)不(bu)充(chong)分,釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)中(zhong)(zhong)會(hui)存在(zai)脆性(xing)(xing)(xing)化(hua)(hua)合物(wu)(wu),釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)的(de)(de)(de)強(qiang)度(du)(du)(du)(du)(du)和(he)塑(su)性(xing)(xing)(xing)都會(hui)下降。而(er)且(qie)在(zai)一(yi)(yi)(yi)定(ding)范圍內,釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)越(yue)寬,釬(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)(feng)中(zhong)(zhong)脆性(xing)(xing)(xing)相(xiang)越(yue)多,接頭(tou)(tou)的(de)(de)(de)強(qiang)度(du)(du)(du)(du)(du)和(he)塑(su)性(xing)(xing)(xing)越(yue)低。
在釬焊實際部(bu)件時,有時部(bu)件加工(gong)精度(du)或(huo)裝配精度(du)很(hen)難保(bao)證釬縫(feng)間隙很(hen)小,適當地提(ti)高釬焊溫度(du)或(huo)延長(chang)保(bao)溫時間可增大(da)最大(da)釬焊間隙,見(jian)圖3-7。當在高溫下長(chang)時間保(bao)溫造成母材晶粒(li)過分長(chang)大(da)或(huo)釬料(liao)對(dui)母材溶蝕(shi)過度(du)時,也可在焊后接頭冷(leng)卻到(dao)某一較(jiao)低溫度(du)保(bao)溫,通過擴(kuo)散消(xiao)除釬縫(feng)中的脆性相而增大(da)最大(da)釬焊間隙,見(jian)圖3-8。但(dan)由于磷原子較(jiao)大(da),向母材中擴(kuo)散困難,這(zhe)些措施對(dui)Ni-Cr-P和Ni-P這(zhe)類(lei)釬料(liao)作用不(bu)大(da)。
爐中釬焊時為控制釬料不流到接頭外其他部位或造成工件與卡具的粘連,可在防止釬料潤濕處涂止焊劑。釬焊不銹鋼時可以用TiO2、Y2O3或云母粉與乙醇混和后做止焊劑。